Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137054
Title: Largely lowered transition temperature of a VO2/carbon hybrid phase change material with high thermal emissivity switching ability and near infrared regulations
Authors: Wang, Shancheng
Liu, Guowei
Hu, Peng
Zhou, Yang
Ke, Yujie
Li, Chuanchang
Chen, Jian
Cao, Tun
Long, Yi
Keywords: Engineering::Materials
Issue Date: 2018
Source: Wang, S., Liu, G., Hu, P., Zhou, Y., Ke, Y., Li, C., . . . Long, Y. (2018). Largely lowered transition temperature of a VO2/carbon hybrid phase change material with high thermal emissivity switching ability and near infrared regulations. Advanced Materials Interfaces, 5(21), 1801063-. doi:10.1177/01461672187709993
Journal: Advanced Materials Interfaces 
Abstract: Vanadium oxide (VO2) as a phase changing material possesses abrupt infrared (IR) transmission and thermal emissivity changing during the metal–insulator transition across transition temperature (τc) of 68 °C. However, the high τc, moderate IR transmission and emissivity regulating ability limits its applications in various fields. A VO2/carbon hybrid phase change material fabricated via homemade plasma enhanced chemical vapor deposition is reported. The material shows a best reported thermal emissivity contrast (0.44) among the experimental values, a largely lowered τc (45 °C), promising a near IR-regulation ability with enhanced photothermal effect in smart windows applications. The theoretical calculation results proved that the improvement of emissivity contrast is due to the hybridization of carbon. This work provides a new approach to synthesize VO2 hybrid materials, which have wide applications in camouflage, sensing, and smart windows.
URI: https://hdl.handle.net/10356/137054
ISSN: 2196-7350
DOI: 10.1002/admi.201801063
Schools: School of Materials Science & Engineering 
Organisations: Campus for Research Excellence and Technological Enterprise (CREATE) 
Singapore-HUJ Alliance for Research and Enterprise (SHARE) 
Nanomaterials for Energy and Energy-Water Nexus (NEW) 
Rights: This is the peer reviewed version of the following article: Wang, S., Liu, G., Hu, P., Zhou, Y., Ke, Y., Li, C., . . . Long, Y. (2018). Largely lowered transition temperature of a VO2/carbon hybrid phase change material with high thermal emissivity switching ability and near infrared regulations. Advanced Materials Interfaces, 5(21), 1801063-, which has been published in final form at https://doi.org/10.1002/admi.201801063. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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