Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137421
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dc.contributor.authorLiu, Zhihaoen_US
dc.contributor.authorLunchev, Andrey V.en_US
dc.contributor.authorLi, Wenen_US
dc.contributor.authorRuan, Shuangchenen_US
dc.contributor.authorRachid Yazamien_US
dc.contributor.authorGrimsdale, Andrew Cliveen_US
dc.contributor.authorSu, Haibinen_US
dc.date.accessioned2020-03-25T03:43:24Z-
dc.date.available2020-03-25T03:43:24Z-
dc.date.issued2019-
dc.identifier.citationLiu, Z., Lunchev, A. V., Li, W., Ruan, S., Rachid Yazami, Grimsdale, A. C., & Su, H. (2019). Electrochemical properties of anthracene-based lithium-solvated electron solutions. ACS Omega, 4(3), 4707-4711. doi:10.1021/acsomega.8b03621en_US
dc.identifier.issn2470-1343en_US
dc.identifier.urihttps://hdl.handle.net/10356/137421-
dc.description.abstractThe conductivity and open-circuit voltage (OCV) of lithium-solvated electron solutions (LiSESs) based on anthracene in tetrahydrofuran were studied by both experimental measurements and density functional theory calculations with a range-separated functional based on the M06 form and the Solvation Model based on Density (SMD). The OCV was found to decrease with increasing temperature and the ratio of lithium to anthracene. The enthalpy change (ΔH) of LiSESs was the internal energy change of the cell reaction. The conductivity of LiSESs exhibited a weakly metallic-like behavior. The electron transport was facilitated by molecular collisions promoted by the formation of dimeric structures as intermediates. The conductivity of LiSESs at 295.15 K presents positive correlation with the entropy change (ΔS) associated with the variation in the ratio of lithium to poly-aromatic hydrocarbon, including p-terphenyl, anthracene, and triphenylene.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofACS Omegaen_US
dc.rights© 2019 American Chemical Society. This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.en_US
dc.subjectEngineering::Materialsen_US
dc.titleElectrochemical properties of anthracene-based lithium-solvated electron solutionsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1021/acsomega.8b03621-
dc.description.versionPublished versionen_US
dc.identifier.pmid31459657-
dc.identifier.scopus2-s2.0-85062610795-
dc.identifier.issue3en_US
dc.identifier.volume4en_US
dc.identifier.spage4707en_US
dc.identifier.epage4711en_US
dc.subject.keywordsLithium-solvated Electron Solutionsen_US
dc.subject.keywordsAnthraceneen_US
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item.grantfulltextopen-
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