Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137625
Title: Experimental and theoretical investigation of mesoporous MnO2 nanosheets with oxygen vacancies for high-efficiency catalytic DeNOx
Authors: Liu, Jia
Wei, Yajuan
Li, Pei-Zhou
Zhang, Peipei
Su, Wei
Sun, Yan
Zou, Ruqiang
Zhao, Yanli
Keywords: Science::Chemistry
Issue Date: 2018
Source: Liu, J., Wei, Y., Li, P.-Z., Zhang, P., Su, W., Sun, Y., ... Zhao, Y. (2018). Experimental and theoretical investigation of mesoporous MnO2 nanosheets with oxygen vacancies for high-efficiency catalytic DeNOx. ACS Catalysis, 8, 3865-3874. doi:10.1021/acscatal.8b00267
Journal: ACS Catalysis
Abstract: A solvent-free synthetic method was employed for the construction of mesoporous α-MnO2 nanosheets. Benefiting from a solid interface reaction, the obtained MnO2 nanosheets with large oxygen vacancies exhibit a high surface area of up to 339 m2/g and a mesopore size of 4 nm. The MnO2 nanosheets as a catalyst were applied in NH3-assisted selective catalytic reduction (NH3-SCR) of DeNOx at a relatively low temperature range. The conversion efficiency could reach 100% under a gas hourly space velocity (GHSV) of 700000 h−1 at 100 °C. To gain insight into the mechanism about NH3-SCR of nitric oxide on the MnO2 nanosheets, temperature-programmed desorption of NH3, a density functional theory study, and in situ diffuse reflectance infrared Fourier transform spectra were carried out, revealing the cooperative effect of catalytic sites on the reduction of nitric oxide. This work provides a strategy for the facile preparation of porous catalysts in low-temperature DeNOx.
URI: https://hdl.handle.net/10356/137625
ISSN: 2155-5435
DOI: 10.1021/acscatal.8b00267
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.8b00267
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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