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|Title:||Boron analogue of vinylidene dication supported by phosphines||Authors:||Lu, Wei
|Keywords:||Science::Chemistry||Issue Date:||2018||Source:||Lu, W., Li, Y., Ganguly, R., & Kinjo, R. (2018). Boron analogue of vinylidene dication supported by phosphines. Journal of the American Chemical Society, 140(4), 1255-1258. doi:10.1021/jacs.7b13068||Journal:||Journal of the American Chemical Society||Abstract:||In the presence of a catalytic amount of heavier tetrylene dichlorides, an allenic diborene 1 undergoes a 1,3-hydrogen shift to afford a terminal diborene 2, which can be deemed a boron analogue of vinylidene dication stabilized by Lewis bases. X-ray diffraction analysis and computational studies revealed that 2 involves a conjugative interaction between the C═C and B═B π-orbitals. The reaction of 2 with ZnBr2 afforded the corresponding isolable complex 3, in which two boon centers coordinate to the Zn atom asymmetrically.||URI:||https://hdl.handle.net/10356/137699||ISSN:||0002-7863||DOI:||10.1021/jacs.7b13068||Rights:||© 2018 American Chemical Society. All rights reserved.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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