Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137706
Title: Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile
Authors: Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2018
Source: Su, Y., Li, Y., Ganguly, R., & Kinjo, R. (2018). Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile. Angewandte Chemie International Edition, 57(26), 7846-7849. doi:10.1002/anie.201803938
Journal: Angewandte Chemie International Edition
Abstract: An annulated 1,3,2,5‐diazadiborinine with 14 π electrons has been synthesized and fully characterized. Experimental and computational studies revealed that this compound features a rather small HOMO–LUMO gap, which leads to enhanced reactivity towards small molecules. Thus, the 1,3,2,5‐diazadiborinine readily cleaves the H−H bond of dihydrogen and an N−H bond of ammonia under mild conditions. Moreover, it reacts with 2,6‐dimethylphenylisonitrile in a [4+1] cycloaddition at room temperature.
URI: https://hdl.handle.net/10356/137706
ISSN: 1433-7851
DOI: 10.1002/anie.201803938
Rights: © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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