Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137720
Title: Facile activation of homoatomic σ bonds in white phosphorus and diborane by a diboraallene
Authors: Lu, Wei
Xu, Kai
Li, Yongxin
Hirao, Hajime
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2018
Source: Lu, W., Xu, K., Li, Y., Hirao, H., & Kinjo, R. (2018). Facile activation of homoatomic σ bonds in white phosphorus and diborane by a diboraallene. Angewandte Chemie International Edition, 57(48), 15691-15695. doi:10.1002/anie.201808357
Journal: Angewandte Chemie International Edition
Abstract: Metal‐free activation of homoatomic E−E σ bonds (E=P, B) in white phosphorus (P4) and bis(catecholato)diboron (B2cat2) with a 1,2‐diboraallene 1 is reported. The 1:1 and 1:2 reactions of P4 with 1 afford BnP4 cages (2: n=2, 3: n=4), whereas a stoichiometric mixture of 1 and B2cat2 undergoes homonuclear catenation through the addition of the B−B σ bond of B2cat2 across the B=B double bond of 1 (i.e. diboration), which leads to the formation of a tetraborane (4) featuring a B4 chain.
URI: https://hdl.handle.net/10356/137720
ISSN: 1433-7851
DOI: 10.1002/anie.201808357
Rights: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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