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https://hdl.handle.net/10356/137723| Title: | Macrolide synthesis through intramolecular oxidative cross‐coupling of alkenes | Authors: | Jiang, Bing Zhao, Meng Li, Shu-Sen Xu, Yun-He Loh, Teck-Peng |
Keywords: | Science::Chemistry | Issue Date: | 2018 | Source: | Jiang, B., Zhao, M., Li, S.-S., Xu, Y.-H., & Loh, T.-P. (2018). Macrolide synthesis through intramolecular oxidative cross‐coupling of alkenes. Angewandte Chemie International Edition, 57(2), 555-559. doi:10.1002/anie.201710601 | Journal: | Angewandte Chemie International Edition | Abstract: | A RhIII‐catalyzed intramolecular oxidative cross‐coupling between double bonds for the synthesis of macrolides is described. Under the optimized reaction conditions, macrocycles containing a diene moiety can be formed in reasonable yields and with excellent chemo‐ and stereoselectivity. This method provides an efficient approach to synthesize macrocyclic compounds containing a 1,3‐conjugated diene structure. | URI: | https://hdl.handle.net/10356/137723 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.201710601 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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