Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137742
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dc.contributor.authorXing, Pengyaoen_US
dc.contributor.authorLi, Yongxinen_US
dc.contributor.authorWang, Yangen_US
dc.contributor.authorLi, Pei-Zhouen_US
dc.contributor.authorChen, Hongzhongen_US
dc.contributor.authorPhua, Fiona Soo Zengen_US
dc.contributor.authorZhao, Yanlien_US
dc.date.accessioned2020-04-13T04:20:36Z-
dc.date.available2020-04-13T04:20:36Z-
dc.date.issued2018-
dc.identifier.citationXing, P., Li, Y., Wang, Y., Li, P.-Z., Chen, H., Phua, F. S. Z., & Zhao, Y. (2018). Water‐binding‐mediated gelation/crystallization and thermosensitive superchirality. Angewandte Chemie International Edition, 57(26), 7774-7779. doi:10.1002/anie.201802825en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttps://hdl.handle.net/10356/137742-
dc.description.abstractDetermination of molecular structural parameters of hydrophobic cholesterol–naphthalimide conjugates for water binding capabilities as well as their moisture‐sensitive supramolecular self‐assembly were revealed. Water binding was a key factor in leading trace water‐induced crystallization against gelation in apolar solvent. Ordered water molecules entrapped in self‐assembly arrays revealed by crystal structures behave as hydrogen‐bonding linkers to facilitate three‐dimensional growth into crystals rather than one‐dimensional gel nanofibers. Water binding was also reflected on the supramolecular chirality inversion of vesicle self‐assembly in aqueous media via heating‐induced dehydration. Structural parameters that favor water binding were evaluated in detail, which could help rationally design organic building units for advancing soft materials, crystal engineering, and chiral recognition.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofAngewandte Chemie International Editionen_US
dc.rights© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.en_US
dc.subjectScience::Chemistryen_US
dc.titleWater‐binding‐mediated gelation/crystallization and thermosensitive superchiralityen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1002/anie.201802825-
dc.identifier.pmid29696772-
dc.identifier.scopus2-s2.0-85048795836-
dc.identifier.issue26en_US
dc.identifier.volume57en_US
dc.identifier.spage7774en_US
dc.identifier.epage7779en_US
dc.subject.keywordsChirality Inversionen_US
dc.subject.keywordsCrystallizationen_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
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