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Title: Isolation and reactivity of a chlorogermyliumylidene featuring two Ge – Cl units
Authors: Su, Yuanting
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2018
Source: Su, Y., Li, Y., Ganguly, R., & Kinjo, R. (2018). Isolation and reactivity of a chlorogermyliumylidene featuring two Ge – Cl units. European Journal of Inorganic Chemistry, 2018(20-21), 2228-2231. doi:10.1002/ejic.201701483
Journal: European Journal of Inorganic Chemistry
Abstract: Deprotonation of 1‐mesityl‐4,5‐diphenyl‐2‐imidazole 1 with nBuLi, followed by salt metathesis reaction with GeCl2·dioxane complex, led to the formation of the chlorogermyliumylidene 2 bearing two Ge–Cl units, which has been isolated and fully characterized by standard spectroscopic and X‐ray diffraction analysis. Structural and NMR spectroscopic data as well as computational studies revealed that the positive charge mainly resides on the Ge atom between two nitrogen atoms. Reduction of 2 with an excess amount of lithium metal resulted in Ge–Ge bond formation concomitant with elimination of one of the Ge atoms of 2, to give rise to the digermylenedilithium compound 3 involving intramolecular coordination of the imines and the lone pairs to the Li atoms.
ISSN: 1434-1948
DOI: 10.1002/ejic.201701483
Rights: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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