Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/137763
Title: | Carbene-catalyzed α-carbon amination of chloroaldehydes for enantioselective access to dihydroquinoxaline derivatives | Authors: | Huang, Ruoyan Chen, Xingkuan Mou, Chengli Luo, Guoyong Li, Yongjia Li, Xiangyang Xue, Wei Jin, Zhichao Chi, Robin Yonggui |
Keywords: | Science::Chemistry::Organic chemistry | Issue Date: | 2019 | Source: | Huang, R., Chen, X., Mou, C., Luo, G., Li, Y., Li, X., … Chi, R. Y. (2019). Carbene-catalyzed α-carbon amination of chloroaldehydes for enantioselective access to dihydroquinoxaline derivatives. Organic Letters, 21(11), 4340-4344. doi:10.1021/acs.orglett.9b01520 | Journal: | Organic Letters | Abstract: | An NHC-catalyzed α-carbon amination of chloroaldehydes was developed. Cyclohexadiene-1,2-diimines are used as amination reagents and four-atom synthons. Our reaction affords optically enriched dihydroquinoxalines that are core structures in natural products and synthetic bioactive molecules. | URI: | https://hdl.handle.net/10356/137763 | ISSN: | 1523-7060 | DOI: | 10.1021/acs.orglett.9b01520 | Schools: | School of Physical and Mathematical Sciences | Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.9b01520 | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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Carbene-Catalyzed a-Carbon Amination of Chloroaldehydes for Enantioselective Access to Dihydroquinoxaline Derivatives.pdf | 898.41 kB | Adobe PDF | View/Open |
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