Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137777
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dc.contributor.authorWang, Honglingen_US
dc.contributor.authorWang, Yuhuangen_US
dc.contributor.authorChen, Xingkuanen_US
dc.contributor.authorMou, Chenglien_US
dc.contributor.authorYu, Shuyanen_US
dc.contributor.authorChai, Huifangen_US
dc.contributor.authorJin, Zhichaoen_US
dc.contributor.authorChi, Robin Yongguien_US
dc.date.accessioned2020-04-14T06:45:30Z-
dc.date.available2020-04-14T06:45:30Z-
dc.date.issued2019-
dc.identifier.citationWang, H., Wang, Y., Chen, X., Mou, C., Yu, S., Chai, H., ... , Chi, R. Y. (2019). Chiral nitroarenes as enantioselective single-electron-transfer oxidants for carbene-catalyzed radical reactions. Organic Letters, 21(18), 7440-7444. doi:10.1021/acs.orglett.9b02736en_US
dc.identifier.issn1523-7060en_US
dc.identifier.urihttps://hdl.handle.net/10356/137777-
dc.description.abstractA new class of chiral oxidants is developed. These readily accessible oxidants contain a nitro group for oxidation and a chiral sulfonamide moiety for stereoselectivity control. The chiral information from the oxidants can effectively transfer to the substrates in carbene-catalyzed β-hydroxylation of enals via single-electron-transfer radical processes. We expect these oxidants to find unique applications in other asymmetric oxidations and oxygen-atom-transferring reactions.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipASTAR (Agency for Sci., Tech. and Research, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofOrganic Lettersen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.9b02736en_US
dc.subjectScience::Chemistry::Organic chemistryen_US
dc.titleChiral nitroarenes as enantioselective single-electron-transfer oxidants for carbene-catalyzed radical reactionsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.orglett.9b02736-
dc.description.versionAccepted versionen_US
dc.identifier.pmid31478384-
dc.identifier.scopus2-s2.0-85072546160-
dc.identifier.issue18en_US
dc.identifier.volume21en_US
dc.identifier.spage7440en_US
dc.identifier.epage7444en_US
dc.subject.keywordsEnantioselectiveen_US
dc.subject.keywordsChiralityen_US
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