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dc.contributor.authorLi, Binen_US
dc.contributor.authorYildirim, Erolen_US
dc.contributor.authorLi, Weien_US
dc.contributor.authorQi, Dianpengen_US
dc.contributor.authorYu, Jiancanen_US
dc.contributor.authorWei, Jiaqien_US
dc.contributor.authorLiu, Zhiyuanen_US
dc.contributor.authorSun, Zhenkunen_US
dc.contributor.authorLiu, Yongen_US
dc.contributor.authorKong, Biaoen_US
dc.contributor.authorXue, Zhaotengen_US
dc.contributor.authorLiu, Zhuangjianen_US
dc.contributor.authorYang, Shuo-Wangen_US
dc.contributor.authorChen, Xiaodongen_US
dc.contributor.authorZhao, Dongyuanen_US
dc.identifier.citationLi, B., Yildirim, E., Li, W., Qi, D., Yu, J., Wei, J., . . ., Zhao, D. (2018). CoFe2O4 Nanocrystals Mediated Crystallization Strategy for Magnetic Functioned ZSM‐5 Catalysts. Advanced Functional Materials, 28(32), 1802088-. doi:10.1002/adfm.201802088en_US
dc.description.abstractZeolites have many applications in the petrochemical and fine chemical industry and their functionalization does expand the spectrum of potentials. However, the integration of functional nanocrystals into zeolite frameworks with controlled size, dispersion, and crystallization behavior still remains a significant challenge. Here, a new synthesis of magnetic functioned ZSM-5 zeolite catalysts via a CoFe2O4 nanocrystal mediated crystallization strategy is reported. It is found that high crystallinity of CoFe2O4 nanocrystals results in a well-dispersed encapsulation of them into a single-crystal of ZSM-5 due to non-further-grown nanocrystals during the fast ZSM-5 growth. On the contrary, low crystallinity of CoFe2O4 nanocrystals leads to the polycrystalline zeolite growth due to the secondary growth of nanocrystals accompanied by the zeolite crystallization and large lattice mismatch between them. The successful encapsulation of small CoFe2O4 nanocrystals (≈4 nm) into single crystals lies on the preattachment of them into solid silica gel. During the growth of ZSM-5 crystals, no secondary growth of nanocrystals happens and its motion is restricted. The encapsulation of magnetic CoFe2O4 nanocrystals not only endows magnetic function into zeolites for the first time, but also does not impact catalytic performance of ZSM-5 in acetalization of cyclohexanone with methanol, which is highly promising in catalytic industries.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.relation.ispartofAdvanced Functional Materialsen_US
dc.rights© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Advanced Functional Materials and is made available with permission of WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.titleCoFe2O4 nanocrystals mediated crystallization strategy for magnetic functioned ZSM-5 catalystsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen_US
dc.description.versionAccepted versionen_US
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