Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137824
Title: Hydrodehalogenation of aryl halides through direct electrolysis
Authors: Ke, Jie
Wang, Hongling
Zhou, Liejin
Mou, Chengli
Zhang, Jingjie
Pan, Lutai
Chi, Robin Yonggui
Keywords: Science::Chemistry::Organic chemistry::Organic electrochemistry
Issue Date: 2019
Source: Ke, J., Wang, H., Zhou, L., Mou, C., Zhang, J., Pan, L., & Chi, R. Y. (2019). Hydrodehalogenation of aryl halides through direct electrolysis. Chemistry – A European Journal, 25(28), 6911-6914. doi:10.1002/chem.201901082
Journal: Chemistry – A European Journal
Abstract: A catalyst- and metal-free electrochemical hydrodehalogenation of aryl halides is disclosed. Our reaction by a flexible protocol is operated in an undivided cell equipped with an inexpensive graphite rod anode and cathode. Trialkylamines nBu3 N/Et3 N behave as effective reductants and hydrogen atom donors for this electrochemical reductive reaction. Various aryl and heteroaryl bromides worked effectively. The typically less reactive aryl chlorides and fluorides can also be smoothly converted. The utility of our method is demonstrated by detoxification of harmful pesticides and hydrodebromination of a dibrominated biphenyl (analogues of flame-retardants) in gram scale.
URI: https://hdl.handle.net/10356/137824
ISSN: 0947-6539
DOI: 10.1002/chem.201901082
Rights: This is the peer reviewed version of the following article: Ke, J., Wang, H., Zhou, L., Mou, C., Zhang, J., Pan, L., & Chi, R. Y. (2019). Hydrodehalogenation of aryl halides through direct electrolysis. Chemistry – A European Journal, 25(28), 6911-6914, which has been published in final form at https://doi.org/10.1002/chem.201901082. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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