Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137893
Title: N-Heterocyclic carbene catalyzed radical coupling of aldehydes with redox-active esters
Authors: Song, Runjiang
Chi, Robin Yonggui
Keywords: Science::Chemistry::Organic chemistry
Issue Date: 2019
Source: Song, R., & Chi, R. Y. (2019). N-Heterocyclic carbene catalyzed radical coupling of aldehydes with redox-active esters. Angewandte Chemie International Edition, 58(26), 8628-8630. doi:10.1002/anie.201902792
Journal: Angewandte Chemie International Edition
Abstract: N-Heterocyclic carbene catalyzed radical reactions are challenging and underdeveloped. In a recent study, Ohmiya, Nagao and co-workers found that aldehyde carbonyl carbon centers can be coupled with alkyl radicals under NHC catalysis. An elegant aspect of this study is the use of a redox-active carboxylic ester that behaves as an single-electron oxidant to convert the Breslow intermediate into a radical adduct and concurrently release an alkyl radical intermediate as a reaction partner.
URI: https://hdl.handle.net/10356/137893
ISSN: 1433-7851
DOI: 10.1002/anie.201902792
Rights: This is the peer reviewed version of the following article: Song, R., & Chi, Y. R. (2019). N-Heterocyclic carbene catalyzed radical coupling of aldehydes with redox-active esters. Angewandte Chemie International Edition, 58(26), 8628-8630, which has been published in final form at https://doi.org/10.1002/anie.201902792. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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