Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/137971
Title: Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization
Authors: Ge, Yicen
Chen, Chen
Sim, Xuan Ming
Zheng, Jie
Goto, Atsushi
Keywords: Science::Chemistry
Issue Date: 2020
Source: Ge, Y., Chen, C., Sim, X. M., Zheng, J., & Goto, A. (2020). Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization. Macromolecular Rapid Communications, 41(5), e1900623-. doi:10.1002/marc.201900623
Journal: Macromolecular Rapid Communications
Abstract: ABC-type miktoarm star copolymers are synthesized using a single living radical polymerization (organocatalyzed living radical polymerization) via a "combinatorial" approach. The arm A is poly(butyl acrylate), the arm B is poly(methyl methacrylate), and the arm C encompasses hydrophobic and hydrophilic polyacrylates. A poly(butyl acrylate) with a vinyl chain end (macromonomer) is synthesized. A poly(methyl methacrylate) is subsequently connected to the reactive vinyl group to generate diblock copolymer. From the junction of the diblock copolymer, polymer C grew to yield star copolymers. An amphiphilic star copolymer is also synthesized, and its self-assembly structure is studied in an aqueous solution.
URI: https://hdl.handle.net/10356/137971
ISSN: 1521-3927
DOI: 10.1002/marc.201900623
Rights: This is the peer reviewed version of the following article: Ge, Y., Chen, C., Sim, X. M., Zheng, J., & Goto, A. (2020). Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization. Macromolecular Rapid Communications, 41(5), e1900623-. doi:10.1002/marc.201900623, which has been published in final form at 10.1002/marc.201900623. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: embargo_20210308
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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