Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/138275
Title: | Addition of N-heterocyclic carbene catalyst to aryl esters induces remote C-Si bond activation and benzylic carbon functionalization | Authors: | Wang, Hongling Chen, Xingkuan Li, Yongjia Wang, Jilan Wu, Shuquan Xue, Wei Yang, Song Chi, Robin Yonggui |
Keywords: | Science::Chemistry::Organic chemistry | Issue Date: | 2018 | Source: | Wang, H., Chen, X., Li, Y., Wang, J., Wu, S., Xue, W., . . ., Chi, R. Y. (2017). Addition of N-heterocyclic carbene catalyst to aryl esters induces remote C-Si bond activation and benzylic carbon functionalization. Organic letters, 20(2), 333-336. doi:10.1021/acs.orglett.7b03544 | Journal: | Organic letters | Abstract: | Through the incorporation of a silicon atom to an aryl carboxylic ester substrate, the resulting C-Si bond can be activated via the addition of a carbene catalyst on a remote site. This strategy allows for efficient functionalization of the benzylic sp3-carbons of aryl carboxylic esters. | URI: | https://hdl.handle.net/10356/138275 | ISSN: | 1523-7060 | DOI: | 10.1021/acs.orglett.7b03544 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2017 American Chemical Society. All rights reserved. This paper was published in Organic letters and is made available with permission of American Chemical Society. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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Addition of N-Heterocyclic Carbene Catalyst to Aryl Esters Induces Remote C–Si Bond Activation and Benzylic Carbon Functionalization.pdf | 967.73 kB | Adobe PDF | ![]() View/Open |
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