Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/138302
Title: Carbene-catalyzed LUMO activation of alkyne esters for access to functional pyridines
Authors: Mou, Chengli
Wu, Jichang
Huang, Zhijian
Sun, Jun
Jin, Zhichao
Chi, Robin Yonggui
Keywords: Science::Chemistry::Organic chemistry
Issue Date: 2017
Source: Mou, C., Wu, J., Huang, Z., Sun, J., Jin, Z., & Chi, R. Y. (2017). Carbene-catalyzed LUMO activation of alkyne esters for access to functional pyridine. Chemical Communications, 53(100), 13359-13362. doi:10.1039/C7CC08039E
Journal: Chemical Communications
Abstract: A carbene-catalyzed LUMO activation of a,b-unsaturated alkyne esters is reported. This catalytic process allows for effective reactions of alkyne esters with enamides to synthesize functional pyridines via simple protocols. A previously unexplored unsaturated alkyne acyl azolium intermediate is involved in the key step of the reaction.
URI: https://hdl.handle.net/10356/138302
ISSN: 1359-7345
DOI: 10.1039/C7CC08039E
Rights: © 2017 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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