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Title: Mesoporous implantable Pt/SrTiO3:C,N nanocuboids delivering enhanced photocatalytic H2-production activity via plasmon-induced interfacial electron transfer
Authors: Tamiolakis, Ioannis
Liu, Dong
Xiao, Fang-Xing
Xie, Jian
Papadas, Ioannis T.
Salim, Teddy
Liu, Bin
Zhang, Qichun
Choulis, Stelios A.
Armatas, Gerasimos S.
Keywords: Science::Chemistry
Issue Date: 2018
Source: Tamiolakis, I., Liu, D., Xiao, F.-X., Xie, J., Papadas, I. T., Salim, T., . . . Armatas, G. S. (2018). Mesoporous implantable Pt/SrTiO3:C,N nanocuboids delivering enhanced photocatalytic H2-production activity via plasmon-induced interfacial electron transfer. Applied Catalysis B: Environmental, 236, 338-347. doi:10.1016/j.apcatb.2018.05.036
Journal: Applied Catalysis B: Environmental
Abstract: Band edge engineering of semiconductor nanostructures is one of the most appealing approaches to enhance light absorption, carrier separation and, ultimately, solar to fuel conversion efficiency. In this study, we devise a facile polymer-assisted sol-gel chemical method to prepare highly porous, crystalline implanted SrTiO3 (STO) nanoparticles and demonstrate their performance for photocatalytic hydrogen generation from water. X-ray scattering, electron microscopy, and nitrogen physisorption data corroborate that the as-made catalysts comprise 100-nm-sized nanocuboid particles containing a highly internal porous structure (BET surface area ∼176 m2 g−1) with uniform mesopores (ca. 5.8 nm in diameter). Interestingly, a partial substitution of N and C for O is attained in STO lattice with this synthetic protocol, according to the elemental analysis, and infrared (IR) and X-ray photoelectron spectroscopy (XPS) studies. Compared to STO:C,N, the STO:C,N mesoporous decorated with Pt nanoparticles (ca. 3 nm) present unique attributes that allow for an impressive improvement of up to 74-fold in photocatalytic H2-production activity. By combining UV-vis/NIR optical absorption, photoluminescence, Raman and electrochemical impedance spectroscopy, we show that this improved performance arises from the unique nanostructure, which provides massive surface active sites, and the proper alignment of defect states and conduction band-edge position of the STO:C,N semiconductor with respect to the interband transitions of metal, which permit efficient plasmon-induced interfacial electron transfer between the Pt-STO:C,N junction.
ISSN: 0926-3373
DOI: 10.1016/j.apcatb.2018.05.036
Rights: © 2018 Elsevier B.V. All rights reserved. This paper was published in Applied Catalysis B: Environmental and is made available with permission of Elsevier B.V.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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