Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/138627
Title: Rationally designed three-layered Cu2S@Carbon@MoS2 hierarchical nanoboxes for efficient sodium storage
Authors: Fang, Yongjin
Luan, Deyan
Chen, Ye
Gao, Shuyan
Lou, David Xiong Wen
Keywords: Engineering::Chemical engineering
Issue Date: 2020
Source: Fang, Y., Luan, D., Chen, Y., Gao, S., & Lou, D. X. W. (2020). Rationally designed three-layered Cu2S@Carbon@MoS2 hierarchical nanoboxes for efficient sodium storage. Angewandte Chemie International Edition, 59(18), 7178-7183. doi:10.1002/anie.201915917
Journal: Angewandte Chemie International Edition
Abstract: Hybrid materials, integrating the merits of individual components, are ideal structures for efficient sodium storage. However, the construction of hybrid structures with decent physical/electrochemical properties is still challenging. Now, the elaborate design and synthesis of hierarchical nanoboxes composed of three-layered Cu2 S@carbon@MoS2 as anode materials for sodium-ion batteries is reported. Through a facile multistep template-engaged strategy, ultrathin MoS2 nanosheets are grown on nitrogen-doped carbon-coated Cu2 S nanoboxes to realize the Cu2 S@carbon@MoS2 configuration. The design shortens the diffusion path of electrons/Na+ ions, accommodates the volume change of electrodes during cycling, enhances the electric conductivity of the hybrids, and offers abundant active sites for sodium uptake. By virtue of these advantages, these three-layered Cu2 S@carbon@MoS2 hierarchical nanoboxes show excellent electrochemical properties in terms of decent rate capability and stable cycle life.
URI: https://hdl.handle.net/10356/138627
ISSN: 1433-7851
DOI: 10.1002/anie.201915917
Rights: © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Angewandte Chemie International Edition and is made available with permission of Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SCBE Journal Articles

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