Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/138673
Title: Direct substitution of secondary and tertiary alcohols to generate sulfones under catalyst- and additive-free conditions
Authors: Liu, Yanan
Xie, Peizhong
Sun, Zuolian
Wo, Xiangyang
Gao, Cuiqing
Fu, Weishan
Loh, Teck-Peng
Keywords: Science::Chemistry
Issue Date: 2018
Source: Liu, Y., Xie, P., Sun, Z., Wo, X., Gao, C., Fu, W., & Loh, T.-P. (2018). Direct substitution of secondary and tertiary alcohols to generate sulfones under catalyst- and additive-free conditions. Organic Letters, 20(17), 5353-5356. doi:10.1021/acs.orglett.8b02188
Journal: Organic Letters
Abstract: An environmentally benign protocol that affords propargylic sulfones containing highly congested carbon centers from easily accessible alcohols and sulfinic acids with water as the only byproduct is reported. The reaction proceeded via an in situ dehydrative cross-coupling process by taking advantage of the synergetic actions of multiple hydrogen bonds rather than relying on an external catalyst and/or additives to achieve high product distribution.
URI: https://hdl.handle.net/10356/138673
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.8b02188
Rights: © 2018 American Chemical Society. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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