Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/138741
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dc.contributor.authorLi, Jiaen_US
dc.contributor.authorLuo, Manen_US
dc.contributor.authorSheng, Xingchaoen_US
dc.contributor.authorHua, Haimingen_US
dc.contributor.authorYao, Weiweien_US
dc.contributor.authorPullarkat, Sumod Appukuttanen_US
dc.contributor.authorXu, Lien_US
dc.contributor.authorMa, Mengtaoen_US
dc.date.accessioned2020-05-12T05:54:35Z-
dc.date.available2020-05-12T05:54:35Z-
dc.date.issued2018-
dc.identifier.citationLi, J., Luo, M., Sheng, X., Hua, H., Yao, W., Pullarkat, S. A., . . . Ma, M. (2018). Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds. Organic Chemistry Frontiers, 5(24), 3538-3547. doi:10.1039/c8qo00720aen_US
dc.identifier.issn2052-4110en_US
dc.identifier.urihttps://hdl.handle.net/10356/138741-
dc.description.abstractA series of unsymmetrical β-diketimine coordinated magnesium(i) complexes have been successfully synthesized via reductions of related magnesium(ii) halide complexes with a sodium reducing reagent in toluene or n-hexane solution. All the unsymmetrical magnesium(i) complexes prepared have been crystallographically and spectroscopically characterized. It was found, for the first time, that these well-defined unsymmetrical magnesium(i) complexes were highly active pre-catalysts for the hydroboration of alkynes, nitriles, aldehydes and ketones.en_US
dc.language.isoenen_US
dc.relation.ispartofOrganic Chemistry Frontiersen_US
dc.rights© 2018 The Partner Organisations. All rights reserved.en_US
dc.subjectScience::Chemistryen_US
dc.titleUnsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compoundsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1039/c8qo00720a-
dc.identifier.scopus2-s2.0-85058177710-
dc.identifier.issue24en_US
dc.identifier.volume5en_US
dc.identifier.spage3538en_US
dc.identifier.epage3547en_US
dc.subject.keywordsβ-diketiminate Magnesiumen_US
dc.subject.keywordsHydroborationen_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
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