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https://hdl.handle.net/10356/138741
Title: | Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds | Authors: | Li, Jia Luo, Man Sheng, Xingchao Hua, Haiming Yao, Weiwei Pullarkat, Sumod Appukuttan Xu, Li Ma, Mengtao |
Keywords: | Science::Chemistry | Issue Date: | 2018 | Source: | Li, J., Luo, M., Sheng, X., Hua, H., Yao, W., Pullarkat, S. A., . . . Ma, M. (2018). Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds. Organic Chemistry Frontiers, 5(24), 3538-3547. doi:10.1039/c8qo00720a | Journal: | Organic Chemistry Frontiers | Abstract: | A series of unsymmetrical β-diketimine coordinated magnesium(i) complexes have been successfully synthesized via reductions of related magnesium(ii) halide complexes with a sodium reducing reagent in toluene or n-hexane solution. All the unsymmetrical magnesium(i) complexes prepared have been crystallographically and spectroscopically characterized. It was found, for the first time, that these well-defined unsymmetrical magnesium(i) complexes were highly active pre-catalysts for the hydroboration of alkynes, nitriles, aldehydes and ketones. | URI: | https://hdl.handle.net/10356/138741 | ISSN: | 2052-4110 | DOI: | 10.1039/c8qo00720a | Rights: | © 2018 The Partner Organisations. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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