Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/138741
Title: Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds
Authors: Li, Jia
Luo, Man
Sheng, Xingchao
Hua, Haiming
Yao, Weiwei
Pullarkat, Sumod Appukuttan
Xu, Li
Ma, Mengtao
Keywords: Science::Chemistry
Issue Date: 2018
Source: Li, J., Luo, M., Sheng, X., Hua, H., Yao, W., Pullarkat, S. A., . . . Ma, M. (2018). Unsymmetrical β-diketiminate magnesium(i) complexes : syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds. Organic Chemistry Frontiers, 5(24), 3538-3547. doi:10.1039/c8qo00720a
Journal: Organic Chemistry Frontiers
Abstract: A series of unsymmetrical β-diketimine coordinated magnesium(i) complexes have been successfully synthesized via reductions of related magnesium(ii) halide complexes with a sodium reducing reagent in toluene or n-hexane solution. All the unsymmetrical magnesium(i) complexes prepared have been crystallographically and spectroscopically characterized. It was found, for the first time, that these well-defined unsymmetrical magnesium(i) complexes were highly active pre-catalysts for the hydroboration of alkynes, nitriles, aldehydes and ketones.
URI: https://hdl.handle.net/10356/138741
ISSN: 2052-4110
DOI: 10.1039/c8qo00720a
Rights: © 2018 The Partner Organisations. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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