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dc.contributor.authorTanis-Kanbur, Melike Begumen_US
dc.contributor.authorVelioğlu, Sadiyeen_US
dc.contributor.authorTanudjaja, Henry Jonathanen_US
dc.contributor.authorHu, Xiaoen_US
dc.contributor.authorChew, Jia Weien_US
dc.identifier.citationTanis-Kanbur, M. B., Velioğlu, S., Tanudjaja, H. J., Hu, X., & Chew, J. W. (2018). Understanding membrane fouling by oil-in-water emulsion via experiments and molecular dynamics simulations. Journal of Membrane Science, 566, 140-150. doi:10.1016/j.memsci.2018.08.067en_US
dc.description.abstractMembrane-based filtration is promising for the treatment of oily wastewater with stable micron-sized oil droplets, but is unfortunately limited by the inevitable membrane fouling phenomenon. To advance the understanding on membrane fouling by oil emulsion, this study made use of the direct observation through the membrane (DOTM) technique to experimentally visualize the evolution of fouling and determine critical flux, and also molecular dynamics simulations to unveil the interfacial interactions and behaviors underlying the different fouling behaviors. Three oil emulsion types with similar mean droplet sizes were studied, namely, one without surfactant, one stabilized by sodium dodecyl sulfate (SDS; a negatively charged surfactant) and one stabilized by dodecyltrimethylammonium bromide (DTAB; a positively charged surfactant). DOTM results indicate that the critical flux was the highest in the absence of surfactant and lowest for the DTAB-stabilized ones, while simulation results indicate that the interaction energies are clearly different among the different oil emulsion types. Both hence affirm that the presence of surfactant and different surfactant type distinctly changes the fouling tendencies. The key conclusions on the different fouling tendencies among the three oil emulsion types are summarized as follows. Firstly, the highest critical flux in the absence of any surfactant is linked to greatest oil-water interaction and least oil-membrane interaction, both of which cause the oil molecule to prefer being in the bulk aqueous feed. The radial distribution function (RDF) further substantiates this. Secondly, the higher critical flux exhibited by the SDS-stabilized oil emulsion compared to the DTAB-stabilized ones could be attributed to the negative charge of the former. Simulations affirm the comparatively greater oil-membrane repulsion through the RDF profile, lower oil-membrane interaction and higher oil-water interaction of the SDS-stabilized oil emulsion. Thirdly, despite surfactants generally have a stabilizing effect on oil emulsions, DOTM images show that coalescence was most extensive for the DTAB-stabilized oil emulsion, because of the greatest oil-membrane attraction and least oil-oil repulsion. Coupling both experiments and simulations, this study enhanced the mechanistic understanding on the effect of surfactant on membrane fouling by emulsions of the same oil.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.description.sponsorshipEDB (Economic Devt. Board, S’pore)en_US
dc.relation.ispartofJournal of Membrane Scienceen_US
dc.rights© 2018 Elsevier B.V. All rights reserved.en_US
dc.subjectEngineering::Chemical engineeringen_US
dc.titleUnderstanding membrane fouling by oil-in-water emulsion via experiments and molecular dynamics simulationsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.contributor.schoolSchool of Materials Science & Engineeringen_US
dc.contributor.schoolInterdisciplinary Graduate School (IGS)en_US
dc.contributor.organizationSingapore Membrane Technology Centreen_US
dc.contributor.organizationEnvironmental Chemistry and Materials Centreen_US
dc.contributor.researchNanyang Environment and Water Research Instituteen_US
dc.subject.keywordsMembrane Foulingen_US
dc.subject.keywordsOil-in-water Emulsionen_US
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