Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/139390
Title: Hydrogenation of fluorographite and fluorographene : an easy way to produce highly hydrogenated graphene
Authors: Bouša, Daniel
Mazánek, Vlastimil
Sedmidubský, David
Jankovský, Ondřej
Pumera, Martin
Sofer, Zdeněk
Keywords: Science::Chemistry
Issue Date: 2018
Source: Bouša, D., Mazánek, V., Sedmidubský, D., Jankovský, O., Pumera, M., & Sofer, Z. (2018). Hydrogenation of fluorographite and fluorographene : an easy way to produce highly hydrogenated graphene. Chemistry - A European Journal, 24(33), 8350-8360. doi:10.1002/chem.201800236
Journal: Chemistry - A European Journal
Abstract: Fluorographene is an excellent precursor for the synthesis of graphene derivatives. Relative to pure graphene, fluorographene possesses higher reactivity and, in comparison with graphene oxide, is also homogenous in composition, which enables the preparation of well-defined materials. Recently, it has been shown that several graphene derivatives can be synthesized from fluorographene, thus yielding various products such as graphene acid or alkylated graphene. This study focuses on the hydrogenation of fluorographene by using various hydrogenation reactions, including the use complex hydrides and solvated electrons in different media. In addition, a comparison of these reactions shows that fluorinated graphite has significantly lower reactivity than fluorographene. The conversion rates of these reactions are higher when fluorographene is used relative to fluorographite. These reactions can be used to tune the hydrogen/fluorine composition on a graphene backbone.
URI: https://hdl.handle.net/10356/139390
ISSN: 0947-6539
DOI: 10.1002/chem.201800236
Rights: This is the accepted version of the following article: Bouša, D., Mazánek, V., Sedmidubský, D., Jankovský, O., Pumera, M., & Sofer, Z. (2018). Hydrogenation of fluorographite and fluorographene : an easy way to produce highly hydrogenated graphene. Chemistry - A European Journal, 24(33), 8350-8360, which has been published in final form at dx.doi.org/10.1002/chem.201800236. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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