Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/139491
Title: Reactivity of a base-stabilized germanium(I) dimer toward group 9 metal(I) chloride and dimanganese decacarbonyl
Authors: Muhammad Luthfi Ismail
Liu, Fu-Quan
Yim, Wai-Leung
Ganguly, Rakesh
Li, Yongxin
So, Cheuk-Wai
Keywords: Science::Chemistry
Issue Date: 2017
Source: Muhammad Luthfi Ismail., Liu, F.-Q., Yim, W.-L., Ganguly, R., Li, Y., & So, C.-W. (2017). Reactivity of a base-stabilized germanium(I) dimer toward group 9 metal(I) chloride and dimanganese decacarbonyl. Inorganic chemistry, 56(9), 5402–5410. doi:10.1021/acs.inorgchem.7b00503
Journal: Inorganic chemistry
Abstract: The reactivity of the 2-imino-5,6-methylenedioxylphenylgermanium(I) dimer toward group 9 metal(I) chloride and dimanganese decacarbonyl is described. [LGe:]2 (1, L = 2-imino-5,6-methylenedioxylphenyl) underwent a disproportionation reaction with 1.5 equiv of group 9 metal(I) chloride [MCl(cod)]2 (M = Rh, Ir) in toluene to afford a mixture of the group 9 metallogermylene-chlorometal(I) complexes [LGeμ-{M(cod)}2Cl] (M = Rh (2), Ir (4)) and chlorogermylene-chlorometal(I) complexes [L(Cl)GeM(cod)Cl] (M = Rh (3), Ir (5)), respectively. The disproportionation property of 1 is further evidenced by its reaction with 0.5 equiv of Mn2(CO)10 in refluxing toluene to form a mixture of the manganogermylene dimer [(LGe)μ-{Mn(CO)4}]2 (7) and free ligand [LH] (8). Compounds 2-5, 7, and 8 were elucidated by NMR spectroscopy, X-ray crystallography, and DFT calculations, respectively.
URI: https://hdl.handle.net/10356/139491
ISSN: 0020-1669
DOI: 10.1021/acs.inorgchem.7b00503
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.7b00503.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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