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https://hdl.handle.net/10356/139819| Title: | Alkene synthesis using phosphonium ylides as umpolung reagents | Authors: | Vu, Minh Duy Leng, Wei-Lin Hsu, Hao-Cheng Liu, Xue-Wei |
Keywords: | Science::Chemistry | Issue Date: | 2018 | Source: | Vu, M. D., Leng, W.-L., Hsu, H.-C., & Liu, X.-W. (2019). Alkene synthesis using phosphonium ylides as umpolung reagents. Asian Journal of Organic Chemistry, 8(1), 93-96. doi:10.1002/ajoc.201800586 | Journal: | Asian Journal of Organic Chemistry | Abstract: | We report a transformation between a well‐known nucleophile, phosphonium ylide, and an electrophile. Subsequent ylide‐ylide coupling achieves unusual (Z )‐selectivity as compared to the conventional Wittig olefination. The synthesis of medium‐sized ring olefins has also been demonstrated, together with a one‐pot olefination from activated halides. | URI: | https://hdl.handle.net/10356/139819 | ISSN: | 2193-5807 | DOI: | 10.1002/ajoc.201800586 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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