Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/140009
Full metadata record
DC FieldValueLanguage
dc.contributor.authorZhao, Junen_US
dc.contributor.authorJayakumar, Anjalien_US
dc.contributor.authorLee, Jong-Minen_US
dc.date.accessioned2020-05-26T03:56:50Z-
dc.date.available2020-05-26T03:56:50Z-
dc.date.issued2018-
dc.identifier.citationZhao, J., Jayakumar, A., & Lee, J.-M. (2018). Bifunctional sulfonated MoO3 – ZrO2 binary oxide catalysts for the one-step synthesis of 2,5-diformylfuran from fructose. ACS Sustainable Chemistry & Engineering, 6(3), 2976-2982. doi:10.1021/acssuschemeng.7b02671en_US
dc.identifier.issn2168-0485en_US
dc.identifier.urihttps://hdl.handle.net/10356/140009-
dc.description.abstractSulfonated MoO3–ZrO2 binary oxides (MZS) with different Mo/Zr ratios were synthesized and applied as bifunctional catalysts for the simple one-pot transformation of fructose to 2,5-diformylfuran (DFF). The presence of Brønsted acid sites and the molybdenum oxide species in the catalysts is responsible for the high efficiency and good activity of the catalysts. The former contributes to a high yield of 5-hydroxymethylfurfural (HMF) in the fructose dehydration, and the latter has the role of catalyzing the selective aerobic oxidation of the resulted HMF into DFF. In optimized reaction conditions, DFF yield of 74% with fructose of 100% can be achieved in a one-step reaction. The catalyst can be separated, simply regenerated, and reused without any significant loss in activity, indicating its great potential for the industrial mass production of DFF from fructose.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofACS Sustainable Chemistry & Engineeringen_US
dc.rights© 2018 American Chemical Society. All rights reserved.en_US
dc.subjectEngineering::Chemical engineeringen_US
dc.titleBifunctional sulfonated MoO3 – ZrO2 binary oxide catalysts for the one-step synthesis of 2,5-diformylfuran from fructoseen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.identifier.doi10.1021/acssuschemeng.7b02671-
dc.identifier.scopus2-s2.0-85043255372-
dc.identifier.issue3en_US
dc.identifier.volume6en_US
dc.identifier.spage2976en_US
dc.identifier.epage2982en_US
dc.subject.keywordsFructoseen_US
dc.subject.keywords5-Hydroxymethylfurfuralen_US
item.fulltextNo Fulltext-
item.grantfulltextnone-
Appears in Collections:SCBE Journal Articles

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.