Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/140527
Title: Water in rechargeable multivalent‐ion batteries : an electrochemical Pandora's box
Authors: Manalastas, William, Jr.
Kumar, Sonal
Verma, Vivek
Zhang, Liping
Yuan, Du
Srinivasan, Madhavi
Keywords: Engineering::Materials
Issue Date: 2018
Source: Manalastas, W., Jr., Kumar, S., Verma, V., Zhang, L., Yuan, D., & Srinivasan, M. (2019). Water in rechargeable multivalent‐ion batteries : an electrochemical Pandora's box. ChemSusChem, 12(2), 379-396. doi:10.1002/cssc.201801523
Project: NRF2017-08/NRF2016NRF-NRFI001-22 
Journal: ChemSusChem 
Abstract: Multivalent‐ion batteries built on water‐based electrolytes represent energy storage at suitable price points, competitive performance, and enhanced safety. However, to comply with modern energy‐density requirements, the battery must be reversible within an operating voltage window greater than 1.23 V or the electrochemical stability limits of free water. Taking advantage of its powerful solvation and catalytic activities, adding water to electrolyte preparations can unlock a wider gamut of liquid mixtures compared with strictly nonaqueous systems. However, a point‐by‐point sweep of all potential formulations is arduous and ineffective without some form of systematic rationalization. The present Review consolidates recent progress, pitfalls, limits, and insights critical to expediting aqueous electrolyte designs to boost multivalent‐ion battery outputs.
URI: https://hdl.handle.net/10356/140527
ISSN: 1864-5631
DOI: 10.1002/cssc.201801523
Rights: This is the accepted version of the following article: Manalastas, W., Jr., Kumar, S., Verma, V., Zhang, L., Yuan, D., & Srinivasan, M. (2019). Water in rechargeable multivalent‐ion batteries : an electrochemical Pandora's box. ChemSusChem, 12(2), 379-396. doi:10.1002/cssc.201801523, which has been published in final form at https://doi.org/10.1002/cssc.201801523. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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