Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/140681
Title: Tuning of the degree of charge transfer and the electronic properties in organic binary compounds by crystal engineering : a perspective
Authors: Jiang, Hui
Hu, Peng
Ye, Jun
Zhang, Keke K.
Long, Yi
Hu, Wenping
Kloc, Christian
Keywords: Engineering::Materials
Issue Date: 2017
Source: Jiang, H., Hu, P., Ye, J., Zhang, K. K., Long, Y., Hu, W., & Kloc, C. (2018). Tuning of the degree of charge transfer and the electronic properties in organic binary compounds by crystal engineering : a perspective. Journals of Materials Chemistry C, 6(8), 1884-1902. doi:10.1039/c7tc04982j
Journal: Journal of Materials Chemistry C
Abstract: Organic charge-transfer compounds have received significant attention because of their tunable electronic properties, ranging from insulators to superconductors. It has been demonstrated that these compounds can be applied to both organic semiconducting active materials and organic conductors by appropriate molecular design. 7,7,8,8-Tetracyanoquinodimethane (TCNQ) and FxTCNQ (x = 1, 2, 4) as acceptors and aromatic hydrocarbons form a variety of compounds in which the degree of charge transfer (DCT) is adjustable. The donor, acceptor, and stoichiometry of organic charge-transfer compounds are the main factors for tuning the DCT. Tuning of the DCT by crystal engineering allows control of the delocalized electrons and thus the physical properties of materials in a range that is not available in one-component organic solids.
URI: https://hdl.handle.net/10356/140681
ISSN: 2050-7526
DOI: 10.1039/c7tc04982j
Rights: © 2018 The Royal Society of Chemistry. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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