Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/141978
Title: | Asperidine B : total synthesis and structure correction | Authors: | Waddell, Lachlan J. N. Watts, Olivia F. B. Saetang, Praphatsorn Rukachaisirikul, Vatcharin Bates, Roderick Wayland |
Keywords: | Science::Chemistry | Issue Date: | 2020 | Source: | Waddell, L. J. N., Watts, O. F. B., Saetang, P., Rukachaisirikul, V., & Bates, R. W. (2020). Asperidine B : total synthesis and structure correction. Tetrahedron Letters, 61(27), 152078-. doi:10.1016/j.tetlet.2020.152078 | Journal: | Tetrahedron Letters | Abstract: | A synthesis of the proposed structure of asperidine B is reported, involving a tandem hydroformylation-condensation reaction, a diastereoselective dihydroxylation and the addition of an organozinc reagent to an iminium ion. As the spectroscopic data for the synthetic material is not in agreement with that of the natural product, the structure of asperidine B is reassigned as (+)-preussin. | URI: | https://hdl.handle.net/10356/141978 | ISSN: | 0040-4039 | DOI: | 10.1016/j.tetlet.2020.152078 | DOI (Related Dataset): | https://doi.org/10.21979/N9/OD7MHF | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2020 Elsevier Ltd. All rights reserved. This paper was published in Tetrahedron Letters and is made available with permission of Elsevier Ltd. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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File | Description | Size | Format | |
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1Asperidine Tet lett revised.pdf | 251.74 kB | Adobe PDF | View/Open |
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