Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/141978
Title: Asperidine B : total synthesis and structure correction
Authors: Waddell, Lachlan J. N.
Watts, Olivia F. B.
Saetang, Praphatsorn
Rukachaisirikul, Vatcharin
Bates, Roderick Wayland
Keywords: Science::Chemistry
Issue Date: 2020
Source: Waddell, L. J. N., Watts, O. F. B., Saetang, P., Rukachaisirikul, V., & Bates, R. W. (2020). Asperidine B : total synthesis and structure correction. Tetrahedron Letters, 61(27), 152078-. doi:10.1016/j.tetlet.2020.152078
Journal: Tetrahedron Letters
Abstract: A synthesis of the proposed structure of asperidine B is reported, involving a tandem hydroformylation-condensation reaction, a diastereoselective dihydroxylation and the addition of an organozinc reagent to an iminium ion. As the spectroscopic data for the synthetic material is not in agreement with that of the natural product, the structure of asperidine B is reassigned as (+)-preussin.
URI: https://hdl.handle.net/10356/141978
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2020.152078
DOI (Related Dataset): https://doi.org/10.21979/N9/OD7MHF
Schools: School of Physical and Mathematical Sciences 
Rights: © 2020 Elsevier Ltd. All rights reserved. This paper was published in Tetrahedron Letters and is made available with permission of Elsevier Ltd.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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