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https://hdl.handle.net/10356/142685| Title: | Two-dimensional and emission-tunable : an unusual perovskite constructed from lindqvist-type [Pb6Br19]7- nanoclusters | Authors: | Li, Xinxiong Ha Do, T. Thu Águila, Andrés Granados Del Huang, Yinjuan Chen, Wangqiao Li, Yongxin Ganguly, Rakesh Morris, Samuel Xiong, Qihua Li, Dong-Sheng Zhang, Qichun |
Keywords: | Engineering::Materials | Issue Date: | 2018 | Source: | Li, X., Ha Do, T. T., Águila, A. G. D., Huang, Y., Chen, W., Li, Y., . . . Zhang, Q. (2018). Two-dimensional and emission-tunable : an unusual perovskite constructed from lindqvist-type [Pb6Br19]7- nanoclusters. Inorganic Chemistry, 57(22), 14035–14038. doi:10.1021/acs.inorgchem.8b02535 | Project: | AcRF Tier 1 RG 2/17 AcRF Tier 1 RG 111/17 AcRF Tier 1 RG 8/16 AcRF Tier 1 RG 114/16 MOE 2017-T2-1-021 AcRF Tier 1 RG 194/17 AcRF Tier 1 RG 113/16 |
Journal: | Inorganic Chemistry | Abstract: | Preparing low-dimensional perovskite materials with novel building units is highly desirable because such materials have already been demonstrated to show unusual physical properties. In this report, we first reported a new and unusual two-dimensional perovskite framework, [B(HIm)4]4Pb13Br38 (1), constructed from novel Lindqvist-type [Pb6Br19]7- nanoclusters. The as-prepared material shows good water resistance and chemical/heat stability. More importantly, 1 has been proven to exhibit temperature/excitation-wavelength-dependent emission. A possible mechanism has been provided. | URI: | https://hdl.handle.net/10356/142685 | ISSN: | 0020-1669 | DOI: | 10.1021/acs.inorgchem.8b02535 | Schools: | School of Materials Science and Engineering School of Physical and Mathematical Sciences |
Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b02535 | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| Inorganic Chemistry Two-Dimensional and Emission Tunable ...pdf | 267.96 kB | Adobe PDF |  View/Open |
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