Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/142837
Title: Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivatives
Authors: Barik, Chandan Kr
Ganguly, Rakesh
Li, Yongxin
Leong, Weng Kee
Keywords: Science::Chemistry
Issue Date: 2019
Source: Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2019). Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivatives. Journal of Organometallic Chemistry, 887, 5-11. doi:10.1016/j.jorganchem.2019.02.022
Journal: Journal of Organometallic Chemistry
Abstract: The ruthenacyclic carbamoyl complexes [Ru (2-NHC(O)C5H4N) (CO)2(X) (NCMe)] (X = Cl, Br) (1) and [Ru (2-NHC(O)C5H4N) (CO)2 (2-S-Py)] (2) undergo substitution reactions with organophosphines to afford derivatives which are prone to a redistribution of the phosphine ligand. We have studied these redistribution reactions experimentally and computationally, and proposed an essentially common reaction pathway. The results suggest that the carbamoyl ligand exerts a very strong trans effect.
URI: https://hdl.handle.net/10356/142837
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2019.02.022
Rights: © 2019 Elsevier B.V. All rights reserved. This paper was published in Journal of Organometallic Chemistry and is made available with permission of Elsevier B.V.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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