Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/143477
Title: Boosting electrochemical CO2 reduction on metal–organic frameworks via ligand doping
Authors: Dou, Shuo
Song, Jiajia
Xi, Shibo
Du, Yonghua
Wang, Jiong
Huang, Zhen-Feng
Xu, Jason Zhichuan
Wang, Xin
Keywords: Engineering::Chemical engineering
Issue Date: 2019
Source: Dou, S., Song, J., Xi, S., Du, Y., Wang, J., Huang, Z.-F., ... Wang, X. (2019). Boosting electrochemical CO2 reduction on metal–organic frameworks via ligand doping. Angewandte Chemie International Edition, 58(12), 4041-4045. doi:10.1002/anie.201814711
Journal: Angewandte Chemie International Edition
Abstract: Electrochemical CO2 reduction relies on the availability of highly efficient and selective catalysts. Herein, we report a general strategy to boost the activity of metal–organic frameworks (MOFs) towards CO2 reduction via ligand doping. A strong electron‐donating molecule of 1,10‐phenanthroline was doped into Zn‐based MOFs of zeolitic imidazolate framework‐8 (ZIF‐8) as CO2 reduction electrocatalyst. Experimental and theoretical evidences reveal that the electron‐donating nature of phenanthroline enables a charge transfer, which induces adjacent active sites at the sp2 C atoms in the imidazole ligand possessing more electrons, and facilitates the generation of *COOH, hence leading to improved activity and Faradaic efficiency towards CO production.
URI: https://hdl.handle.net/10356/143477
ISSN: 1433-7851
DOI: 10.1002/anie.201814711
Rights: This is the accepted version of the following article: Dou, S., Song, J., Xi, S., Du, Y., Wang, J., Huang, Z.-F., ... Wang, X. (2019). Boosting electrochemical CO2 reduction on metal – organic frameworks via ligand doping. Angewandte Chemie International Edition, 58(12), 4041-4045. doi:10.1002/anie.201814711, which has been published in final form at https://doi.org/10.1002/anie.201814711. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SCBE Journal Articles

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