Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/143694
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dc.contributor.authorDede, Didemen_US
dc.contributor.authorTaghipour, Nimaen_US
dc.contributor.authorQuliyeva, Ulviyyaen_US
dc.contributor.authorSak, Mustafaen_US
dc.contributor.authorKelestemur, Yusufen_US
dc.contributor.authorGungor, Kivancen_US
dc.contributor.authorDemir, Hilmi Volkanen_US
dc.date.accessioned2020-09-17T02:07:37Z-
dc.date.available2020-09-17T02:07:37Z-
dc.date.issued2019-
dc.identifier.citationDede, D., Taghipour, N., Quliyeva, U., Sak, M., Kelestemur, Y., Gungor, K., & Demir, H. V. (2019). Highly stable multicrown heterostructures of type-II nanoplatelets for ultralow threshold optical gain. Chemistry of Materials, 31(5), 1818-1826. doi:10.1021/acs.chemmater.9b00136en_US
dc.identifier.issn0897-4756en_US
dc.identifier.urihttps://hdl.handle.net/10356/143694-
dc.description.abstractSolution-processed type-II quantum wells exhibit outstanding optical properties, which make them promising candidates for light-generating applications including lasers and LEDs. However, they may suffer from poor colloidal stability under ambient conditions and show strong tendency to assemble into face-to-face stacks. In this work, to resolve the colloidal stability and uncontrolled stacking issues, we proposed and synthesized CdSe/CdSe1–xTex/CdS core/multicrown heteronanoplatelets (NPLs), controlling the amount of Te up to 50% in the crown without changing their thicknesses, which significantly increases their colloidal and photostability under ambient conditions and at the same time preserving their attractive optical properties. Confirming the final lateral growth of CdS sidewalls with X-ray photoelectron spectroscopy, energy-dispersive analysis, and photoelectron excitation spectroscopy, we found that the successful coating of this CdS crown around the periphery of conventional type-II NPLs prevents the unwanted formation of needle-like stacks, which results in reduction of the undesired scattering losses in thin-film samples of these NPLs. Owing to highly efficient exciton funneling from the outmost CdS crown accompanied by the reduced scattering and very low waveguide loss coefficient (∼18 cm–1), ultralow optical gain thresholds of multicrown type-II NPLs were achieved to be as low as 4.15 μJ/cm2 and 2.48 mJ/cm2 under one- and two-photon absorption pumping, respectively. These findings indicate that the strategy of using engineered advanced heterostructures of nanoplatelets provides solutions for improved colloidal stability and enables enhanced photonic performance.en_US
dc.description.sponsorshipAgency for Science, Technology and Research (A*STAR)en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relation.ispartofChemistry of Materialsen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemistry of Materials, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.chemmater.9b00136en_US
dc.subjectScience::Physicsen_US
dc.titleHighly stable multicrown heterostructures of type-II nanoplatelets for ultralow threshold optical gainen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Electrical and Electronic Engineeringen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.chemmater.9b00136-
dc.description.versionAccepted versionen_US
dc.identifier.issue5en_US
dc.identifier.volume31en_US
dc.identifier.spage1818en_US
dc.identifier.epage1826en_US
dc.subject.keywordsSemiconductor Nanocrystalsen_US
dc.subject.keywordsPhotophysicsen_US
dc.description.acknowledgementThe authors gratefully acknowledge the financial support in part from Singapore National Research Foundation under the programs of NRF-NRFI2016-08 and the Science and Engineering Research Council, Agency for Science, Technology and Research (A*STAR) of Singapore and in part from TUBITAK 114F326 and 115E679. H.V.D. also acknowledges support from TUBA. K.G. and Y.K. acknowledge support from TUBITAK BIDEB.en_US
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