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https://hdl.handle.net/10356/143698| Title: | Visible light-mediated trifluoromethylation of fluorinated alkenes via C−F bond cleavage | Authors: | Wu, Liu-Hai Cheng, Jun-Kee Shen, Liang Shen, Zhi-Liang Loh, Teck-Peng |
Keywords: | Engineering::Chemical engineering | Issue Date: | 2018 | Source: | Wu, L.-H., Cheng, J.-K., Shen, L., Shen, Z.-L., & Loh, T.-P. (2018). Visible light-mediated trifluoromethylation of fluorinated alkenes via C−F bond cleavage. Advanced Synthesis & Catalysis, 360(20), 3894-3899. doi:10.1002/adsc.201800740 | Journal: | Advanced Synthesis & Catalysis | Abstract: | A convenient photoredox‐catalyzed defluorinative trifluoromethylation of α‐trifluoromethyl alkenes and gem‐difluoroalkenes is developed. The reactions proceeded efficiently via trifluoromethyl radical addition followed by β‐fluorine elimination process, providing a new entry to multifluorinated alkenes in moderate to good yields with excellent stereoselectivity. | URI: | https://hdl.handle.net/10356/143698 | ISSN: | 1615-4169 | DOI: | 10.1002/adsc.201800740 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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