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Title: Visible light-mediated trifluoromethylation of fluorinated alkenes via C−F bond cleavage
Authors: Wu, Liu-Hai
Cheng, Jun-Kee
Shen, Liang
Shen, Zhi-Liang
Loh, Teck-Peng
Keywords: Engineering::Chemical engineering
Issue Date: 2018
Source: Wu, L.-H., Cheng, J.-K., Shen, L., Shen, Z.-L., & Loh, T.-P. (2018). Visible light-mediated trifluoromethylation of fluorinated alkenes via C−F bond cleavage. Advanced Synthesis & Catalysis, 360(20), 3894-3899. doi:10.1002/adsc.201800740
Journal: Advanced Synthesis & Catalysis
Abstract: A convenient photoredox‐catalyzed defluorinative trifluoromethylation of α‐trifluoromethyl alkenes and gem‐difluoroalkenes is developed. The reactions proceeded efficiently via trifluoromethyl radical addition followed by β‐fluorine elimination process, providing a new entry to multifluorinated alkenes in moderate to good yields with excellent stereoselectivity.
ISSN: 1615-4169
DOI: 10.1002/adsc.201800740
Rights: © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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