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Title: Bioinspired deamination of α-amino acid derivatives catalyzed by a palladium/nickel complex
Authors: Deng, Gongtao
Chen, Jie
Sun, Wangbin
Bian, Kehan
Jiang, Yaojia
Loh, Teck-Peng
Keywords: Engineering::Chemical engineering::Biochemical engineering
Issue Date: 2018
Source: Deng, G., Chen, J., Sun, W., Bian, K., Jiang, Y., & Loh, T.-P. (2018). Bioinspired deamination of α-amino acid derivatives catalyzed by a palladium/nickel complex. Advanced Synthesis & Catalysis, 360(20), 3900-3905. doi:10.1002/adsc.201800823
Journal: Advanced Synthesis & Catalysis
Abstract: An efficient bioinspired deamination method of both natural and unnatural amino acid derivatives has been developed. This method provides easy access to a wide variety of useful α, β‐unsaturated carbonyl compounds. The reaction is realized with two transition metal catalysts (palladium and Nickel) in‐easy handling procedure. A possible reaction pathway is also proposed and the control experiments support the involvement of the palladium‐catalyzed inert sp3 C−H activation as one of the key steps.
ISSN: 1615-4169
DOI: 10.1002/adsc.201800823
Rights: © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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