Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/143832
Title: Acetic acid-assisted fabrication of hierarchical flower-like Bi2O3 for photocatalytic degradation of sulfamethoxazole and rhodamine B under solar irradiation
Authors: Bao, Yueping
Lim, Teik-Thye
Zhong, Ziyi
Wang, Rong
Hu, Xiao
Keywords: Engineering::Civil engineering
Issue Date: 2017
Source: Bao, Y., Lim, T.-T., Zhong, Z., Wang, R., & Hu, X. (2017). Acetic acid-assisted fabrication of hierarchical flower-like Bi2O3 for photocatalytic degradation of sulfamethoxazole and rhodamine B under solar irradiation. Journal of Colloid and Interface Science, 505, 489–499. doi:10.1016/j.jcis.2017.05.070
Journal: Journal of colloid and interface science
Abstract: With the assistance of acetic acid (CH3COOH), a novel 3D flower-like Bi2O3 was synthesized via hydrothermal process followed by calcination. For the first time, the role of CH3COOH as a capping agent in the formation of flower-like structure was investigated. The as-prepared flower-like Bi2O3 had a high activity on the degradation of sulfamethoxazole (SMX) under simulated solar light irradiation due to the narrow band gap of 2.69eV, high percentage of β-Bi2O3 as well as high intensity of polar facets (120) and (200). Meanwhile, the photocatalytic degradation followed apparent pseudo-first-order kinetics. The rate constant (k) increased from 0.7×10-2 to 3.0×10-2min-1 with the catalyst loading varying from 0.5 to 2.0gL-1. Increasing pH values from 3 to 11 led to the decrease of k from 2.2×10-2 to 0.2×10-2min-1, which could be attributed to the electrostatic adsorption between SMX molecules and Bi2O3. The radical quenching experiments showed both direct (h+) and indirect oxidation (OH and O2-) happened in this process.
URI: https://hdl.handle.net/10356/143832
ISSN: 1095-7103
DOI: 10.1016/j.jcis.2017.05.070
Rights: © 2017 Elsevier Inc. All rights reserved. This paper was published in Journal of colloid and interface science and is made available with permission of Elsevier Inc.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:IGS Journal Articles

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