Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/144008
Title: Photo-selective chain end transformation of polyacrylate-iodide using cysteamine and its application to facile single-step preparation of patterned polymer brushes
Authors: Chen, Chen
Wang, Chen-Gang
Xiao, Longqiang
Goto, Atsushi
Keywords: Engineering::Chemical engineering
Issue Date: 2018
Source: Chen, C., Wang, C.-G., Xiao, L., & Goto, A. (2018). Photo-selective chain end transformation of polyacrylate-iodide using cysteamine and its application to facile single-step preparation of patterned polymer brushes. Chemical Communications, 54(97), 13738-13741. doi:10.1039/c8cc08157c
Journal: Chemical Communications
Abstract: Cysteamine, which is an inexpensive and non-toxic aminothiol, was successfully employed as a photo-selective chain end transformation agent of iodo-terminated polymer chains (polymer-I). Polymer-I was selectively transformed to hydrogen-terminated (polymer-H) and thiol-terminated (polymer-SH) polymers with and without UV irradiation, respectively. This method is applicable to acrylate polymers. This photo-selective reaction offered a single-step preparation of patterned polymer brushes with SH and H chain end functionalities as a unique application.
URI: https://hdl.handle.net/10356/144008
ISSN: 1364-548X
DOI: 10.1039/c8cc08157c
Rights: © 2018 Royal Society of Chemistry. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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