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|Title:||Photo-selective chain end transformation of polyacrylate-iodide using cysteamine and its application to facile single-step preparation of patterned polymer brushes||Authors:||Chen, Chen
|Keywords:||Engineering::Chemical engineering||Issue Date:||2018||Source:||Chen, C., Wang, C.-G., Xiao, L., & Goto, A. (2018). Photo-selective chain end transformation of polyacrylate-iodide using cysteamine and its application to facile single-step preparation of patterned polymer brushes. Chemical Communications, 54(97), 13738-13741. doi:10.1039/c8cc08157c||Journal:||Chemical Communications||Abstract:||Cysteamine, which is an inexpensive and non-toxic aminothiol, was successfully employed as a photo-selective chain end transformation agent of iodo-terminated polymer chains (polymer-I). Polymer-I was selectively transformed to hydrogen-terminated (polymer-H) and thiol-terminated (polymer-SH) polymers with and without UV irradiation, respectively. This method is applicable to acrylate polymers. This photo-selective reaction offered a single-step preparation of patterned polymer brushes with SH and H chain end functionalities as a unique application.||URI:||https://hdl.handle.net/10356/144008||ISSN:||1364-548X||DOI:||10.1039/c8cc08157c||Rights:||© 2018 Royal Society of Chemistry. All rights reserved.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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