Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/144106
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dc.contributor.authorLi, Xinxiongen_US
dc.contributor.authorDo, Thi Thu Haen_US
dc.contributor.authordel Águila, A. Granadosen_US
dc.contributor.authorHuang, Yinjuanen_US
dc.contributor.authorChen, Wangqiaoen_US
dc.contributor.authorXiong, Qihuaen_US
dc.contributor.authorZhang, Qichunen_US
dc.date.accessioned2020-10-13T08:59:07Z-
dc.date.available2020-10-13T08:59:07Z-
dc.date.issued2018-
dc.identifier.citationLi, X., Do, T. T. H., del Águila, A. G., Huang, Y., Chen, W., Xiong, Q., & Zhang, Q. (2018). A 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission. Chemistry - An Asian Journal, 13(21), 3185-3189. doi:10.1002/asia.201801292en_US
dc.identifier.issn1861-471Xen_US
dc.identifier.urihttps://hdl.handle.net/10356/144106-
dc.description.abstractSearching novel haloplumbate building units to construct three-dimensional (3D) frameworks is very important and highly desirable because such materials would possess new physical properties and potential applications. Here, by employing tetrakis(N-imidazolemethylene)methane(TIMM) as a structure-directing agent, the first 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6 Br25 ]13- nanoclusters has been successfully prepared under hydrothermal condition, where all Pb2+ centres in [Pb6 Br25 ]13- nanoclusters adopt seven-/eight-coordinated configurations. The as-obtained material is a wide-gap semiconductor (≈3.1 eV) and can be stable up to 320 °C. More importantly, this material has been demonstrated to show temperature-dependent emission. Our results could provide a new strategy to explore novel metal-halide open-framework materials.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.language.isoenen_US
dc.relationAcRF Tier 1 RG 111/17en_US
dc.relationAcRF Tier 1 RG 2/17en_US
dc.relationAcRF Tier 1 RG 114/16en_US
dc.relationAcRF Tier 1 RG 8/16en_US
dc.relationMOE 2017-T2-1-021en_US
dc.relationAcRF Tier 1 RG 113/16en_US
dc.relationAcRF Tier 1 RG 194/17en_US
dc.relation.ispartofChemistry - An Asian Journalen_US
dc.rightsThis is the accepted version of the following article: Li, X., Do, T. T. H., del Águila, A. G., Huang, Y., Chen, W., Xiong, Q., & Zhang, Q. (2018). A 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission. Chemistry - An Asian Journal, 13(21), 3185-3189. doi:10.1002/asia.201801292, which has been published in final form at 10.1002/asia.201801292. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].en_US
dc.subjectEngineering::Materialsen_US
dc.titleA 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emissionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1002/asia.201801292-
dc.description.versionAccepted versionen_US
dc.identifier.pmid30199149-
dc.identifier.issue21en_US
dc.identifier.volume13en_US
dc.identifier.spage3185en_US
dc.identifier.epage3189en_US
dc.subject.keywordsHaloplumbateen_US
dc.subject.keywordsSemiconductoren_US
dc.description.acknowledgementQ.Z acknowledges financial support from AcRF Tier 1 (RG 111/17, RG 2/17, RG 114/16, RG 8/16) and Tier 2 (MOE 2017-T2-1-021), Singapore. Q.X. gratefully acknowledges the funding support from Singapore Ministry of Education via AcRF Tier 1 grants (RG 113/16 and RG 194/17).en_US
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