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https://hdl.handle.net/10356/144106
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DC Field | Value | Language |
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dc.contributor.author | Li, Xinxiong | en_US |
dc.contributor.author | Do, Thi Thu Ha | en_US |
dc.contributor.author | del Águila, A. Granados | en_US |
dc.contributor.author | Huang, Yinjuan | en_US |
dc.contributor.author | Chen, Wangqiao | en_US |
dc.contributor.author | Xiong, Qihua | en_US |
dc.contributor.author | Zhang, Qichun | en_US |
dc.date.accessioned | 2020-10-13T08:59:07Z | - |
dc.date.available | 2020-10-13T08:59:07Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Li, X., Do, T. T. H., del Águila, A. G., Huang, Y., Chen, W., Xiong, Q., & Zhang, Q. (2018). A 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission. Chemistry - An Asian Journal, 13(21), 3185-3189. doi:10.1002/asia.201801292 | en_US |
dc.identifier.issn | 1861-471X | en_US |
dc.identifier.uri | https://hdl.handle.net/10356/144106 | - |
dc.description.abstract | Searching novel haloplumbate building units to construct three-dimensional (3D) frameworks is very important and highly desirable because such materials would possess new physical properties and potential applications. Here, by employing tetrakis(N-imidazolemethylene)methane(TIMM) as a structure-directing agent, the first 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6 Br25 ]13- nanoclusters has been successfully prepared under hydrothermal condition, where all Pb2+ centres in [Pb6 Br25 ]13- nanoclusters adopt seven-/eight-coordinated configurations. The as-obtained material is a wide-gap semiconductor (≈3.1 eV) and can be stable up to 320 °C. More importantly, this material has been demonstrated to show temperature-dependent emission. Our results could provide a new strategy to explore novel metal-halide open-framework materials. | en_US |
dc.description.sponsorship | Ministry of Education (MOE) | en_US |
dc.language.iso | en | en_US |
dc.relation | AcRF Tier 1 RG 111/17 | en_US |
dc.relation | AcRF Tier 1 RG 2/17 | en_US |
dc.relation | AcRF Tier 1 RG 114/16 | en_US |
dc.relation | AcRF Tier 1 RG 8/16 | en_US |
dc.relation | MOE 2017-T2-1-021 | en_US |
dc.relation | AcRF Tier 1 RG 113/16 | en_US |
dc.relation | AcRF Tier 1 RG 194/17 | en_US |
dc.relation.ispartof | Chemistry - An Asian Journal | en_US |
dc.rights | This is the accepted version of the following article: Li, X., Do, T. T. H., del Águila, A. G., Huang, Y., Chen, W., Xiong, Q., & Zhang, Q. (2018). A 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission. Chemistry - An Asian Journal, 13(21), 3185-3189. doi:10.1002/asia.201801292, which has been published in final form at 10.1002/asia.201801292. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html]. | en_US |
dc.subject | Engineering::Materials | en_US |
dc.title | A 3D haloplumbate framework constructed from unprecedented Lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission | en_US |
dc.type | Journal Article | en |
dc.contributor.school | School of Materials Science and Engineering | en_US |
dc.identifier.doi | 10.1002/asia.201801292 | - |
dc.description.version | Accepted version | en_US |
dc.identifier.pmid | 30199149 | - |
dc.identifier.issue | 21 | en_US |
dc.identifier.volume | 13 | en_US |
dc.identifier.spage | 3185 | en_US |
dc.identifier.epage | 3189 | en_US |
dc.subject.keywords | Haloplumbate | en_US |
dc.subject.keywords | Semiconductor | en_US |
dc.description.acknowledgement | Q.Z acknowledges financial support from AcRF Tier 1 (RG 111/17, RG 2/17, RG 114/16, RG 8/16) and Tier 2 (MOE 2017-T2-1-021), Singapore. Q.X. gratefully acknowledges the funding support from Singapore Ministry of Education via AcRF Tier 1 grants (RG 113/16 and RG 194/17). | en_US |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | MSE Journal Articles |
Files in This Item:
File | Description | Size | Format | |
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Chemistry An Asian Journal A 3D Haloplumbate.pdf | 576.37 kB | Adobe PDF | View/Open |
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