Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/144373
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dc.contributor.authorZhen, Wenlongen_US
dc.contributor.authorYuan, Xuen_US
dc.contributor.authorShi, Xiangyanen_US
dc.contributor.authorXue, Canen_US
dc.date.accessioned2020-11-02T06:40:22Z-
dc.date.available2020-11-02T06:40:22Z-
dc.date.issued2020-
dc.identifier.citationZhen, W., Yuan, X., Shi, X., & Xue, C. (2020). Grafting molecular cobalt-oxo cubane catalyst on polymeric carbon nitride for efficient photocatalytic water oxidation. Chemistry - An Asian Journal, 15(16), 2480-2486. doi:10.1002/asia.202000583en_US
dc.identifier.issn1861-471Xen_US
dc.identifier.urihttps://hdl.handle.net/10356/144373-
dc.description.abstractIn this work, we have successfully constructed a cobalt-oxo (CoIII4 O4 ) cubane complex on polymeric carbon nitride (PCN) through pyridine linkage. The covalently grafted CoIII4 O4 cubane units were uniformly distributed on the PCN surface. The product exhibited greatly enhanced photocatalytic activities for water oxidation under visible-light irradiation. Further characterizations and spectroscopic analyses revealed that the grafted CoIII4 O4 cubane units could effectively capture the photogenerated holes from excited PCN, lower the overpotential of oxygen evolution reaction (OER), and serve as efficient catalysts to promote the multi-electron water oxidation process. This work provides new insight into the future development of efficient photocatalysts by grafting molecular catalysts for artificial photosynthesis.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.language.isoenen_US
dc.relation.ispartofChemistry - An Asian Journalen_US
dc.relation.uri10.21979/N9/VO5V9Zen_US
dc.rightsThis is the accepted version of the following article: Zhen, W., Yuan, X., Shi, X., & Xue, C. (2020). Grafting molecular cobalt-oxo cubane catalyst on polymeric carbon nitride for efficient photocatalytic water oxidation. Chemistry - An Asian Journal, 15(16), 2480-2486. doi:10.1002/asia.202000583, which has been published in final form at 10.1002/asia.202000583. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].en_US
dc.subjectEngineering::Materialsen_US
dc.titleGrafting molecular cobalt-oxo cubane catalyst on polymeric carbon nitride for efficient photocatalytic water oxidationen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1002/asia.202000583-
dc.description.versionAccepted versionen_US
dc.identifier.pmid32558309-
dc.identifier.issue16en_US
dc.identifier.volume15en_US
dc.identifier.spage2480en_US
dc.identifier.epage2486en_US
dc.subject.keywordsPhotocatalytic Water Oxidationen_US
dc.subject.keywordsPolymeric Carbon Nitrideen_US
dc.description.acknowledgementThis work is supported by the Ministry of Education, Singapore, under AcRF-Tier2 (MOE2018-T2-1-017) and AcRF-Tier1 (MOE2019-T1-002-012, RG102/19). The authors also thank the support from NTU seed funding for Solar Fuels Laboratory.en_US
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