Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/144757
Title: Incorporation of CoIII acetylacetonate and SNW-1 nanoparticles to tailor O2/N2 separation performance of mixed-matrix membrane
Authors: Samarasinghe, S. A. S. C.
Chuah, Chong Yang
Li, Wen
Sethunga, G. S. M. D. P.
Wang, Rong
Bae, Tae-Hyun
Keywords: Engineering::Chemical engineering
Issue Date: 2019
Source: Samarasinghe, S. A. S. C., Chuah, C. Y., Li, W., Sethunga, G. S. M. D. P., Wang, R., & Bae, T.-H. (2019). Incorporation of CoIII acetylacetonate and SNW-1 nanoparticles to tailor O2/N2 separation performance of mixed-matrix membrane. Separation and Purification Technology, 223, 133–141. doi:10.1016/j.seppur.2019.04.075
Journal: Separation and Purification Technology
Abstract: Mixed-matrix membranes containing a porous organic framework (SNW-1 nanoparticles) and a cobalt-based complex (Co(acac)3) were fabricated using the solution-casting technique for potential applications in O2/N2 separation. The mixed-matrix membranes did not show any appreciable defects. In the following mixture gas permeation testing conducted with a binary mixture composed of 21% O2 and 79% N2 at 1 bar feed pressure and 35 °C, the mixed-matrix membranes containing SNW-1 nanoparticles showed an enhanced O2 permeability, whereas Co(acac)3 improved the O2/N2 selectivity. Hence, with a combination of both nanoparticles and a Cobalt complex in a polymer matrix, a clear synergistic enhancement in O2/N2 separation properties was reported, in which O2 permeability and O2/N2 selectivity were escalated by 33% and 18%, respectively. Solubility-diffusivity analysis in the mixed-matrix membranes revealed that SNW-1 and Co(acac)3 can improve O2 diffusivity and O2 solubility, respectively, resulting in an enhancement of both O2 permeability and O2/N2 selectivity for membranes containing both the nanoparticles and the cobalt complex. Future efforts will be focused on developing asymmetric hollow fiber membranes with thin skin layer comprising both SNW-1 and Co(acac)3.
URI: https://hdl.handle.net/10356/144757
ISSN: 1383-5866
DOI: 10.1016/j.seppur.2019.04.075
Rights: © 2019 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/BY-NC-ND/4.0/).
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SCBE Journal Articles

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