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Title: Diastereoselective intramolecular hydride transfer under brønsted acid catalysis
Authors: Wang, Bin
Gandamana, Dhika Aditya
Gagosz, Fabien
Chiba, Shunsuke
Keywords: Science::Chemistry
Issue Date: 2019
Source: Wang, B., Gandamana, D. A., Gagosz, F., & Chiba, S. (2019). Diastereoselective Intramolecular Hydride Transfer under Brønsted Acid Catalysis. Organic Letters, 21(7), 2298–2301. doi:10.1021/acs.orglett.9b00590
Journal: Organic Letters
Abstract: A diastereoselective hydride transfer process has been developed under Brønsted acid-catalyzed reaction conditions using methyl ethers or acetals as hydride donors and tertiary alcohols or alkenes as precursors of carbocation. The method enables construction of complex molecules having multiple stereogenic centers from rather simple and readily available starting materials with predictable diastereoselective control.
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.9b00590
Rights: © 2019 American Chemical Society. This is an open access article published under an ACS Author Choice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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