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https://hdl.handle.net/10356/144900| Title: | Diastereoselective intramolecular hydride transfer under brønsted acid catalysis | Authors: | Wang, Bin Gandamana, Dhika Aditya Gagosz, Fabien Chiba, Shunsuke |
Keywords: | Science::Chemistry | Issue Date: | 2019 | Source: | Wang, B., Gandamana, D. A., Gagosz, F., & Chiba, S. (2019). Diastereoselective Intramolecular Hydride Transfer under Brønsted Acid Catalysis. Organic Letters, 21(7), 2298–2301. doi:10.1021/acs.orglett.9b00590 | Journal: | Organic Letters | Abstract: | A diastereoselective hydride transfer process has been developed under Brønsted acid-catalyzed reaction conditions using methyl ethers or acetals as hydride donors and tertiary alcohols or alkenes as precursors of carbocation. The method enables construction of complex molecules having multiple stereogenic centers from rather simple and readily available starting materials with predictable diastereoselective control. | URI: | https://hdl.handle.net/10356/144900 | ISSN: | 1523-7060 | DOI: | 10.1021/acs.orglett.9b00590 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2019 American Chemical Society. This is an open access article published under an ACS Author Choice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Diastereoselective intramolecular hydride transfer under bronsted acid catalysis.pdf | 1.15 MB | Adobe PDF |  View/Open |
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