Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/144935
Title: PDMS-coated porous PVDF hollow fiber membranes for efficient recovery of dissolved biomethane from anaerobic effluents
Authors: Sethunga, Godakooru Sethunga Mudiyanselage Dilhara Prebhashwari
Karahan, Huseyin Enis
Wang, Rong
Bae, Tae-Hyun
Keywords: Science::Chemistry
Issue Date: 2019
Source: Sethunga, G. S. M. D. P., Karahan, H. E., Wang, R., & Bae, T.-H. (2019). PDMS-coated porous PVDF hollow fiber membranes for efficient recovery of dissolved biomethane from anaerobic effluents. Journal of Membrane Science, 584, 333-342. doi:10.1016/j.memsci.2019.05.016
Journal: Journal of Membrane Science 
Abstract: This report demonstrates the fabrication of a composite hollow fiber membrane that efficiently recovers dissolved methane (dCH4) from anaerobic wastewater treatment effluents via membrane contactor (MC) process. We first fabricated highly porous hollow fiber membranes (∼85% porosity) using polyvinylidene difluoride (PVDF). Then, we coated the whole structure (bulk), or lumen side of PVDF supports with polydimethylsiloxane (PDMS), a hydrophobic polymer possessing high gas permeability. The adjustment of the concentration of PDMS precursor mix could effectively serve for tuning the performance characteristics of MC membranes and helped suppress membrane wetting, a major performance-reducing factor. Despite their denser skin layers, the lumen-modified membranes demonstrated superior dCH4 recovery flux. Mass transfer analyses have confirmed the importance of preserving bulk porosity while coating the membrane surfaces. The long-term performance tests performed using actual anaerobic effluents suggested that the PDMS coating did not accelerate fouling, such that the lumen-modified MC membranes showed an almost steady flux for 8 days with an anaerobic membrane bioreactor effluent. A high-strength effluent, obtained from an up-flow anaerobic sludge blanket reactor, induced faster fouling. However, we observed only a ∼20% flux decline in a 10-day operation. Thus, we propose that the designed PDMS-PVDF composite membranes are promising for industrial practices.
URI: https://hdl.handle.net/10356/144935
ISSN: 0376-7388
DOI: 10.1016/j.memsci.2019.05.016
Rights: © 2019 Elsevier B.V. All rights reserved. This paper was published in Journal of Membrane Science and is made available with permission of Elsevier B.V.
Fulltext Permission: embargo_20211231
Fulltext Availability: With Fulltext
Appears in Collections:NEWRI Journal Articles

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  Until 2021-12-31
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