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Title: Recent advances in reagent-controlled stereoselective/stereospecific glycosylation
Authors: Yao, Hui
Vu, Minh Duy
Liu, Xue-Wei
Keywords: Science::Chemistry
Issue Date: 2018
Source: Yao, H., Vu, M. D., & Liu, X.-W. (2019). Recent advances in reagent-controlled stereoselective/stereospecific glycosylation. Carbohydrate Research, 473, 72-81. doi:10.1016/j.carres.2018.10.006
Project: NRF2016NRF-NSFC002-005
Journal: Carbohydrate Research
Abstract: The formation of O-glycosidic linkage is arguably one of the most important topics in glycoscience due to the prevalence of O-glycosides in nature. Great efforts have been devoted to this field by many carbohydrate chemists to develop stereoselective/stereospecific glycosylation methodologies. Although glycosyl donor- and acceptor-controlled strategies have significantly progressed, the tedious design and pre-synthesis of substrates could not be avoided. On the other hand, reagent-controlled glycosylation can overcome these challenges and produce the desired selectivity by only altering external factors such as concentration, reagents or other reaction conditions. This mini-review discusses selected recent novel methodologies on reagent-mediated stereo-controlled glycosylation in the last decade, classified by the types of glycosyl donors.
ISSN: 0008-6215
DOI: 10.1016/j.carres.2018.10.006
Rights: © 2018 Elsevier Ltd. All rights reserved. This paper was published in Carbohydrate Research and is made available with permission of Elsevier Ltd.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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