Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/146214
Title: A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene
Authors: Rao, Bin
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2019
Source: Rao, B., & Kinjo, R. (2019). A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene. Angewandte Chemie International Edition, 58(50), 18150-18153. doi:10.1002/anie.201910933
Journal: Angewandte Chemie International Edition
Abstract: A cyclic (alkyl)(amino)germylene undergoes a ring expansion reaction with dibromomesitylborane (MesBBr2 ) to afford a six-membered dibromogermane derivative. In the presence of Lewis bases (PMe3 or Me NHC), reduction of the latter with two equivalents of potassium graphite (KC8 ) gives rise to cyclic (alkyl)(boryl)germylene-Lewis base adducts. Upon heating, the germylene-PMe3 adduct reacts with H2 to yield a germane, probably via a base-free germylene featuring a small HOMO-LUMO gap.
URI: https://hdl.handle.net/10356/146214
ISSN: 1433-7851
DOI: 10.1002/anie.201910933
Rights: This is the accepted version of the following article:Rao, B., & Kinjo, R. (2019). A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene. Angewandte Chemie International Edition, 58(50), 18150-18153. doi:10.1002/anie.201910933, which has been published in final form at https://doi.org/10.1002/anie.201910933. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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