Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/146214
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dc.contributor.authorRao, Binen_US
dc.contributor.authorKinjo, Reien_US
dc.date.accessioned2021-02-02T06:31:51Z-
dc.date.available2021-02-02T06:31:51Z-
dc.date.issued2019-
dc.identifier.citationRao, B., & Kinjo, R. (2019). A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene. Angewandte Chemie International Edition, 58(50), 18150-18153. doi:10.1002/anie.201910933en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttps://hdl.handle.net/10356/146214-
dc.description.abstractA cyclic (alkyl)(amino)germylene undergoes a ring expansion reaction with dibromomesitylborane (MesBBr2 ) to afford a six-membered dibromogermane derivative. In the presence of Lewis bases (PMe3 or Me NHC), reduction of the latter with two equivalents of potassium graphite (KC8 ) gives rise to cyclic (alkyl)(boryl)germylene-Lewis base adducts. Upon heating, the germylene-PMe3 adduct reacts with H2 to yield a germane, probably via a base-free germylene featuring a small HOMO-LUMO gap.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relation.ispartofAngewandte Chemie International Editionen_US
dc.rightsThis is the accepted version of the following article:Rao, B., & Kinjo, R. (2019). A cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germylene. Angewandte Chemie International Edition, 58(50), 18150-18153. doi:10.1002/anie.201910933, which has been published in final form at https://doi.org/10.1002/anie.201910933. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html].en_US
dc.subjectScience::Chemistryen_US
dc.titleA cyclic (alkyl)(boryl)germylene derived from a cyclic (alkyl)(amino)germyleneen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1002/anie.201910933-
dc.description.versionAccepted versionen_US
dc.identifier.pmid31596041-
dc.identifier.scopus2-s2.0-85074628990-
dc.identifier.issue50en_US
dc.identifier.volume58en_US
dc.identifier.spage18150en_US
dc.identifier.epage18153en_US
dc.subject.keywordsBoronen_US
dc.subject.keywordsGermylenesen_US
dc.description.acknowledgementWe are grateful to Nanyang Technological University (NTU) and the Singapore Ministry of Education (MOE2017-T1-002-031) for financial support.en_US
item.grantfulltextopen-
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