Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/147427
Title: Trimetallic spinel NiCo2-xFexO4 nanoboxes for highly efficient electrocatalytic oxygen evolution
Authors: Huang, Yi
Zhang, Song Lin
Lu, Xue Feng
Wu, Zhi-Peng
Luan, Deyan
Lou, David Xiong Wen
Keywords: Engineering::Chemical engineering
Engineering::Materials
Issue Date: 2021
Journal: Angewandte Chemie International Edition
Abstract: The  development of efficient and low-cost electrocatalysts toward the oxygen evolution reaction (OER) is critical for improving the efficiency of several electrochemical energy conversion and storage devices. Here, we report an elaborate design and synthesis of porous Co-based trimetallic spinel oxide nanoboxes ( NiCo 2-x Fe x O 4 NBs ) by a novel meta l- organic framework engaged strategy, which involves chemical etching, cation exchange, and subsequent thermal oxidation processes. Owing to the structural and compositional advantages, the optimized trimetallic NiCo 2-x Fe x O 4 NBs deliver superior electrocatalytic performance for OER with an overpotential of 274 mV at 10 mA cm -2 , a small Tafel slope of 42 mV dec -1 , and good stability in alkaline electrolyte, which is much better than that of Co-based bi/monometallic spinel oxides and even commercial RuO 2 .
URI: https://hdl.handle.net/10356/147427
ISSN: 1433-7851
DOI: 10.1002/anie.202103058
Rights: This is the peer reviewed version of the following article: Huang, Y., Zhang, S. L., Lu, X. F., Wu, Z.-P., Luan, D., & Lou, D. X. W. (2021). Trimetallic spinel NiCo2-xFexO4 nanoboxes for highly efficient electrocatalytic oxygen evolution. Angewandte Chemie International Edition, 60(21), 11841-11846. doi:10.1002/anie.202103058, which has been published in final form at https://doi.org/10.1002/anie.202103058. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SCBE Journal Articles

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