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Title: Site-selective C(sp3)-H amination of thioamide with anthranils under Cp*Co III catalysis
Authors: Liu, Rui-Hua
Shan, Qi-Chao
Hu, Xu-Hong
Loh, Teck-Peng
Keywords: Science::Chemistry
Issue Date: 2019
Source: Liu, R., Shan, Q., Hu, X. & Loh, T. (2019). Site-selective C(sp3)-H amination of thioamide with anthranils under Cp*Co III catalysis. Chemical Communications, 55(38), 5519-5522.
Journal: Chemical Communications
Abstract: Synthetically versatile anthranils as a bifunctional amino source have been employed for the first time to enable direct amination on unactivated C(sp3)-H bonds of thioamides under Cp*CoIII catalysis. The excellent site-selectivity on primary C(sp3)-H bonds is observed for a diverse array of thioamides with high functional group tolerance. Further applicability of the products is also highlighted through a series of interesting synthetic elaborations.
ISSN: 1359-7345
DOI: 10.1039/c9cc01715a
Schools: School of Physical and Mathematical Sciences 
Rights: © 2019 The Royal Society of Chemistry. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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