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https://hdl.handle.net/10356/147433| Title: | Palladium(II)-catalyzed stereospecific alkenyl C-H bond alkylation of allylamines with alkyl iodides | Authors: | Luo, Yun-Cheng Yang, Chao Qiu, Sheng-Qi Liang, Qiu-Ju Xu, Yun-He Loh, Teck-Peng |
Keywords: | Science::Chemistry | Issue Date: | 2019 | Source: | Luo, Y., Yang, C., Qiu, S., Liang, Q., Xu, Y. & Loh, T. (2019). Palladium(II)-catalyzed stereospecific alkenyl C-H bond alkylation of allylamines with alkyl iodides. ACS Catalysis, 9(5), 4271-4276. https://dx.doi.org/10.1021/acscatal.8b04415 | Journal: | ACS Catalysis | Abstract: | A palladium-catalyzed stereospecific alkylation of allylamines with primary and secondary alkyl iodides is described. Isoquinoline-1-carboxamide (IQA) acts as directing group to generate multisubstituted olefin products in cis configuration in moderate to good yields. Mechanistic studies suggest that alkenyl C-H bond activation is the rate-determining step. | URI: | https://hdl.handle.net/10356/147433 | ISSN: | 2155-5435 | DOI: | 10.1021/acscatal.8b04415 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2019 American Chemical Society. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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