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https://hdl.handle.net/10356/148219| Title: | Enantioselective three-component coupling of heteroarenes, cycloalkenes and propargylic acetates | Authors: | Teng, Shenghan Chi, Robin Yonggui Zhou, Steve Jianrong |
Keywords: | Science | Issue Date: | 2021 | Source: | Teng, S., Chi, R. Y. & Zhou, S. J. (2021). Enantioselective three-component coupling of heteroarenes, cycloalkenes and propargylic acetates. Angewandte Chemie International Edition, 60(9), 4491-4495. https://dx.doi.org/10.1002/anie.202014781 | Journal: | Angewandte Chemie International Edition | Abstract: | Asymmetric coupling proceeds efficiently between propargylic acetates, cycloalkenes and electron-rich heteroarenes including indoles, pyrroles, activated furans and thiophenes. 2,3-Disubstituted tetrahydrofurans and pyrrolidines are produced in trans configuration and excellent enantiomeric ratios. The reaction proceeds via Wacker-type attack of nucleophilic heteroarenes on alkenes activated by allenyl PdII species. | URI: | https://hdl.handle.net/10356/148219 | ISSN: | 1521-3773 | DOI: | 10.1002/anie.202014781 | Schools: | School of Physical and Mathematical Sciences | Rights: | This is the peer reviewed version of the following article: Teng, S., Chi, R. Y. & Zhou, S. J. (2021). Enantioselective three-component coupling of heteroarenes, cycloalkenes and propargylic acetates. Angewandte Chemie International Edition, 60(9), 4491-4495. https://dx.doi.org/10.1002/anie.202014781, which has been published in final form at https://doi.org/10.1002/anie.202014781. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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